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Reduction of trivalent chromium in steel-making by-product slag
Waste management
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Get them answered by the team at Tata Steel.
Background

The Linz-Donawitz (LD) process, also known as the basic oxygen steelmaking process, is a method of refining molten pig iron into high-quality steel by blowing pure oxygen into a basic refractory furnace. This process oxidizes impurities like carbon, silicon, phosphorus, and manganese, creating a by-product called LD slag. 

 

Tata Steel Limited, Jamshedpur has developed a patented technology for producing a first of its kind soil conditioner from the LD slag fines which contains all the essential nutrients required for soil health and plant growth, including calcium, sulfur, iron, silicon, phosphorus, and magnesium. 

 

LD Slag is one of the most significant by-products of integrated steel plants around the world, particularly from the perspective of government agencies, regulatory bodies and local authorities. India generates more solid waste per ton of steel (approximately 1.2 tons) compared to Western countries (around 0.55 tons). Among this waste, LD slag contributes substantially, accounting for 120 to 180 kg per ton of steel produced. 

 

Current LD steelmaking processes generate slag with chromium concentrations that exceed acceptable thresholds for reuse, creating a pressing need for scalable solutions that enable this by-product transformation into valuable agricultural inputs. 

 

The typical chemical analysis of LD slag is as shown in the table below. 

Table 1

What we're looking for

We are looking for solutions capable of reducing trivalent chromium concentrations from over 1500 ppm to less than 100 ppm in LD slag, ensuring safety and enabling its sustainable reuse.

Solutions of interest include:
  • Organic processes
  • Inorganic processes
  • Electrochemical extraction
  • Hydrometallurgical treatment
  • Chemical treatment/stabilization
  • Selective leaching
  • High-temperature sintering
  • Crystalline phase transformation
Our must-have requirements are:
  • Ready to implement or requiring minimal adjustments
  • Heavy metal reduction
  • Easy to implement and maintain
Our nice-to-have's are:
  • Percentage constituents of existing elements like Ca, S, Fe, Si, P, and others should not be reduced
What's out of scope:
  • Steel-making processes involving LD converter
  • Solutions that interfere with the operability and productivity of existing processes
Acceptable technology readiness levels (TRL):
Levels 8-9
What we can offer you
Eligible partnership models:
Supply/purchase
Sponsored research
Benefits:
Sponsored Research
Tata Steel would fund the implementation, with the amount of funding to be discussed after the techno-commercial finalization of the proposal, subject to a tentative budget of up to $100,000.
Expertise
Partner will be assigned a representative from Scientific Services at Tata Steel. They will assist the partner during the project as required.
Tools and Technologies
Partners will be allowed to do local customization of instruments. They can also access our lab facilities.
Data
After NDA is signed we can share required data.
Facilities and Services
Partner will be invited to concerned plant or facility for survey and on site understanding of the challenge (video call may also be explored). Required help will be given from Tata Steel to the selected partner.
Reviewers
SS
Shikha Suman
Area Manager Program Management
Q&A with Tata Steel

The Q&A is now closed.

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Q.
Hello Could it be possible to share a mineralogical analysis of the slag or the main mineral phases found in it. Thank you in advance D. Sparis
1
A.
Hi, we have given the chemical analysis of the slag in the background. If this does not work then pls elaborate your requirement.
SS
Shikha Suman, Area Manager Program Management , Tata Steel
January 29, 2025
Is this response helpful?
0
0
A.
I will try to elaborate my requirement. It would be helpful to know the main phases of the slag with an XRD (X-ray diffraction) analysis. This will show which complex oxides exist and help us with the research.
1
A.
Can i have your email id, i would share the detail directly there.
SS
Shikha Suman, Area Manager Program Management , Tata Steel
February 6, 2025
Is this response helpful?
0
0
A.
Thank you very much My email is sparis@mail.ntua.gr
1
Q.
Is it possible to share the (i) slag image and (ii) XRD analysis (mineralogy)? That would tell us two things, (i) which solution of interest would be suitable in your case and (ii) how much Cr2O3 could be eliminated?
1
A.
Hi ,I have shared the attachments in the message.
SS
Shikha Suman, Area Manager Program Management , Tata Steel
February 7, 2025
Is this response helpful?
0
0
Q.
Hello. We have a material that can act as a chromium getter that could be added to the LD process without it degrading. It is at TRL level 3/4, is this too early stage for Tata Steel to be interested in?
1
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