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Removal of salts and sulfates from solid waste
Waste management
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Background

RHI Magnesita is the leading global supplier of high-grade refractory products, systems and solutions which are critical for high-temperature processes in a wide range of industries. With a vertically integrated value chain, RHI Magnesita serves customers around the world, with around 15,000 employees in 47 production sites, 7 recycling facilities and more than 70 sales offices. 

 

To lead sustainable development in refractory industry, RHI Magnesita is working to optimize the use of raw materials in alignment with circular economy best practices. 

 

For this to be possible, in some cases it is necessary to pre-treat circular minerals (recycled refractory products returning from customer) in order to ensure the properties required for final application. This is the case, for example, of raw materials with high alkali content, which need to be removed before use. 

 

The recycling raw materials are, in fact, refractory bricks with varied chemical composition, but divided in two groups: magnesian (>75% MgO) and non-basic(>60%Al2O3). Other compounds include metal oxides such as SiO2, Fe2O3, CaO, among others. 

 

Alkalis occur in this matrix as Na/K salts and sulfates are also present. The content of these compounds can reach up to 3%. They come from the thermal processes in which refractory are used. In these environments, the alkalis are volatilized and infiltrate the bricks. Upon reaching the coldest parts of the refractories, the alkalis are reprecipitated in the form of salts. 

 

We are eager to partner with experts in refractories but also welcome collaborations with researchers and companies focused on adjacent spaces, such as ceramics, composites, construction, mineral processing, extractive metallurgy and mining.

What we're looking for

We are seeking technologies for the removal of alkalis present in post-consumer refractory bricks, with a particular focus on recovering the metal oxides MgO (magnesium oxide) and Al2O3 (aluminum oxide).

Solutions of interest include:
  • Washing
  • Leaching
  • Thermal treatment
Our must-have requirements are:
  • Removal of alkalis to the levels required for final application.
  • The solution cannot interfere with the properties of the refractory products (like refractoriness, mechanical stability, chemical stability, dimensional stability, thermal shock stability, among others).
Our nice-to-have's are:
  • Solutions at higher maturity stage are preferred, but lower maturity solutions are also welcome.
  • Competitive cost (or potential for competitive cost).
  • Applicable on a large scale for Industry (thousands of tons).
What's out of scope:
  • Solutions should not generate any component which is hazardous for health or environment
Acceptable technology readiness levels (TRL):
Levels 3-9
What we can offer you
Eligible partnership models:
Supply/purchase
Licensing
Co-development
Sponsored research
Benefits:
Sponsored Research
Funding is proposal-dependent, based on technology potential
Expertise
We offer the expertise of our team of scientists for collaboration and guidance during the development of the project.
Facilities and Services
Our research and development facilities are fully available for the project. Our R&D centers a count on modern equipment, technical expertise and partnership with leading technological partners.
Reviewers
TR
Tamara Ribeiro
Raw Materials & Minerals Technology Expert
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Juan Rosenzweig
Innovation Manager
Q&A with RHI Magnesita

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